Studies of hydrodynamic flow of aqueous solutions of Dimethyl sulfoxide (DMSO) and Acetonitrile (ACN) at different concentrations through commercially available AcroshieldTM H 69008 composite cellophane membrane at 298.15K are described. The hydrodynamic flow studies have been used to evaluate transport properties such as Permeability coefficient, Lp and Frictional coefficient, Fwm. The data has been analyzed in terms of interactions between membrane and solution.