Some novel compounds are synthesized using the substitution of chlorine in 2,4,6-trichloro-s-triazine by some moieties having structural as well as biological importance like imidazole, benzimidazole and what not which are anti infective agents. In this manner six novel compounds are prepared and they are subjected to antibacterial screening prior to this the synthesized compounds are duly characterized by spectral analysis. These compounds reveal substantive antibacterial activities against some randomly chosen both gram +ve & gram-ve bacteria. The promising results are in support of the fact that the compounds are worth to be optimized for some novel drugs in future. The newly synthesized compounds were characterized using IR, 1 H-NMR.