The quality of groundwater depends on a large number of individual hydrological, physical, chemical and biological factors. Water dissolves the minerals present in the strata of soil it filers through in the case of ground water and, in the case of surface water, the minerals present in the soil over which it flows (rivers/streams) or over which it stands (lakes, ponds, reservoirs). Generally higher proportions of dissolved constituents are found in groundwater than in surface water because of greater interaction of ground water with various materials in geologic strata. The study carried out to find the relationship of fluoride contamination in groundwater through by the interaction method with the help of the physio-chemical parameters using GIS tool. The study emerges with a new perception for the better prediction of contaminants to get a clear vision for the future study.