The phytochemical study on the aerial parts of Linaria reflexa Desf., belonging to the scrophulariaceae family led the isolation and structural elucidation of pectolinarin (1), linariin (2), methyl linoleate (3), apigenin (4), mannitol (5) and pectolinarigenin (6). These compounds were identified by 1D and 2D NMR as well as by mass spectrometry