The fluroquinolone family member ciprofloxacin is well known for its drug design and coordinating ability towards metal ions. The coordination chemistry of this drug with metal ions of biological and pharmaceutical importance is of considerable interest. Novel Ag (I) complex of Ciprofloxacin(CIP) was synthesized and characterized on the basis of their physical properties, (FT-IR and electronic) spectral studies. The TG/DTA analysis of the complexes was carried out. The morphology and size distribution of the complex polymer was obtained by transmission electron microscopy (TEM).